Title: Photooxidation and subsequent biodegradability of recalcitrant tri-alkyl phosphates TCEP and TBP in water.

Authors: Watts, Michael J; Linden, Karl G

Published In Water Res, (2008 Dec)

Abstract: Biodegradable organic carbon (BDOC) from OH radical oxidation (UV-H2O2) of the recalcitrant industrial anti-foaming agents and flame retardants, tri-n-butyl phosphate (TBP) and tris(2-chloroethyl) phosphate (TCEP), was quantified with respect to the fraction of the TBP or TCEP photooxidized. For 50-96% contaminant oxidation via OH, BDOC was similar in solutions of either compound, and ranged from 0.25 to 0.5 mg L(-1) (TBP0 and TCEP0 = 5 mg L(-1)). In addition, for this contaminant oxidation range, complete dehalogenation of TCEP was observed, along with a significant change in pH. Oxidation of TCEP results in both H+ and Cl(-) release, while the TBP mineralization pathway results in CO2, H2O, H+, and PO4(3-). For low microg/L levels of TCEP contamination in treated surface waters, UV-H2O2 oxidation of TCEP or TBP would not be expected to impact pH or chloride concentrations, however, a portion of the TCEP or TBP oxidation products, likely in non-halogenated aldehyde form, would become an available carbon source for bacterial growth in storage, distribution, or during further physical treatment.

PubMed ID: 18986671

MeSH Terms: Acetates/radiation effects; Biodegradation, Environmental*; Chlorides/analysis; Hydrogen Peroxide; Hydrogen-Ion Concentration; Hydroxyl Radical; Organic Chemicals/radiation effects*; Organophosphates/chemistry*; Organophosphates/radiation effects; Oxidation-Reduction; Solutions; Ultraviolet Rays*; Water