Spin Trap Database
Janzen EG; Liu JI-P. Radical addition reactions of 5,5-dimethyl-1-pyrroline-1-oxide. ESR spin trapping with cyclic nitrone. J Magn Reson 9:510-2 (1973) @D@W
All records in the reference are displayed below.
| Spintrap * Radical in Solvent | aN | aH | aN/aH | Comments |
|---|---|---|---|---|
| DMPO * .C tetrahydrofuranyl in BZ | aN = 14.12 G | aH = 17.92 G | 0.79 | THF + BP* |
| DMPO * .C(OH)(CH3)2 in BZ | aN = 14.58 G | aH = 23.91 G | 0.61 | C3H7OH + BP* |
| DMPO * .C6H5 in BZ | aN = 13.76 G | aH = 19.22 G | 0.72 | phenylazotriphenylmethane |
| DMPO * .C6H5 in BZ | aN = 13.79 G | aH = 19.56 G | 0.71 | C6H5OCH3 + BP* |
| DMPO * .CF3 in BZ | aN = 13.22 G | aH = 15.54 G | 0.85 | F=1.01, CF3I + hv |
| DMPO * .CH(CN)C6H5 in BZ | aN = 14.39 G | aH = 20.63 G | 0.70 | C6H5CH2CN + BP* |
| DMPO * .CH(OH)(CH2)2CH3 in BZ | aN = 14.89 G | aH = 22.72 G | 0.66 | C4H9OH + BP* |
| DMPO * .CH(OH)CH3 in BZ | aN = 15.03 G | aH = 22.53 G | 0.67 | EtOH + BP* |
| DMPO * .COC6H5 in BZ | aN = 13.99 G | aH = 15.57 G | 0.90 | C6H5CHO + BP* |
| DMPO * .COH in BZ | aN = 14.03 G | aH = 17.87 G | 0.79 | CH3CHO + BP* |
| DMPO * .CON(CH3)2 in BZ | aN = 14.3 G | aH = 17.37 G | 0.82 | DMF + BP* |
| DMPO * .CONH2 in BZ | aN = 15.23 G | aH = 18.56 G | 0.82 | H2NCHO + BP* |
| DMPO * .Cl in BZ | aN = 19.67 G | aH = N/A | N/A | Cl=3.57, from chlorine |
| DMPO * .F in BZ | aN = 10.83 G | aH = N/A | N/A | F=21.6,H=1.74, difluoro DMPO; AgF2 |
| DMPO * .CH2(CH2)2CH3 in BZ | aN = 14.24 G | aH = 20.41 G | 0.70 | (C4H9)4Pb + hv |
| DMPO * .CH2C6H5 in BZ | aN = 14.16 G | aH = 20.66 G | 0.69 | (C6H5CH2)2Hg + hv |
| DMPO * .CH2CH3 in BZ | aN = 14.2 G | aH = 20.49 G | 0.69 | (C2H5)Hg + hv |
| DMPO * .CH2OH in BZ | aN = 14.66 G | aH = 20.67 G | 0.71 | CH3OH + BP* |
| DMPO * .CH3 in BZ | aN = 14.31 G | aH = 20.52 G | 0.70 | CH3HgI + hv |
| DMPO * .C 1-phenylethyl in BZ | aN = 14.2 G | aH = 20.49 G | 0.69 | C6H5CH2CH3 + BP* |
| DMPO * .H in BZ | aN = 14.43 G | aH = 18.89 G | 0.76 | hv of tri-n-butyl tin hydride |
| DMPO * .O(CH2)3CH3 in BZ | aN = 13.61 G | aH = 6.83 G | 1.99 | H=2.06, n-BuOH + PbOAc4 |
| DMPO * .OCH2CH3 in BZ | aN = 13.22 G | aH = 6.96 G | 1.90 | H=1.89, EtOH + PbOAc4 |
| DMPO * .OCH2CH3 ? in BZ | aN = 14.2 G | aH = 20.49 G | 0.69 | (C2H5)2O + BP* |
| DMPO * .OCH3 in BZ | aN = 13.58 G | aH = 7.61 G | 1.78 | H=1.85, CH3OH + PbOAc4 |
| DMPO * .OC benzoyloxyl in BZ | aN = 12.24 G | aH = 9.63 G | 1.27 | H=0.87(2), (C6H5CO2)2 |
| DMPO * .OC(CH3)3 in BZ | aN = 13.11 G | aH = 7.93 G | 1.65 | H=1.97, di-t--butyperoxalate |
| * .F in BZ | aN = 11.74 G | aH = N/A | N/A | @M3PO;H=1.63,F=52.7,silver difluoride |