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National Institute of Environmental Health Sciences

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Your Environment. Your Health.

Project Publications: University of Cincinnati: Analytical

Superfund Research Program

Analytical

Project Leader: Joseph A. Caruso
Grant Number: P42ES004908
Funding Period: 2001 - 2006

Project-Specific Links

Publications

2013

  • Jayasinghe S, Caruso JA. 2013. Preliminary investigation of Cu-containing proteins in seeds of Brazil nuts by ICPMS and MALDI-MS methods. Int J Mass Spectrom 356:33-36. doi:10.1016/j.ijms.2013.09.014

2012

  • McNear DH, Afton S, Caruso JA. 2012. Exploring the structural basis for selenium/mercury antagonism in Allium fistulosum. Metallomics 4:267-276. doi:10.1039/c2mt00158f PMID:22278221

2011

  • Jayasinghe S, Caruso JA. 2011. Investigation of Se-containing proteins in Bertholletia excelsa HBK (Brazil nuts) by ICPMS, MALDI-MS and LC-ESI-MS methods. Int J Mass Spectrom 307:16-27. doi:10.1016/j.ijms.2010.12.005

2008

  • Afton S, Kubachka KM, Caruso JA, Catron B. 2008. Simultaneous characterization of selenium and arsenic analytes via ion-pairing reversed phase chromatography with inductively coupled plasma and electrospray ionization ion trap mass spectrometry for detection applications to river water, plant extract and urine matrices. J Chromatogr A 1208(1-2):156-163. doi:10.1016/j.chroma.2008.08.077 PMID:18778826
  • Kubachka KM, Richardson DD, Heitkemper DT, Caruso JA. 2008. Detection of chemical warfare agent degradation products in foods using liquid chromatography coupled to inductively coupled plasma mass spectrometry and electrospray ionization mass spectrometry. J Chromatogr A 1202(2):124-131. doi:10.1016/j.chroma.2008.04.028 PMID:18644601

2007

  • Ellis J, Shah M, Kubachka KM, Caruso JA. 2007. Determination of organophosphorus fire retardants and plasticizers in wastewater samples using MAE-SPME with GC-ICPMS and GC-TOFMS detection. J Environ Monit 9(12):1329-36. PMID:18049771
  • Kubachka KM, Meija J, LeDuc DL, Caruso JA. 2007. Selenium volatiles as proxy to the metabolic pathways of selenium in genetically modified Brassica juncea. Environ Sci Technol 41(6):1863-9. PMID:17410776
  • Richardson DD, Caruso JA. 2007. Derivatization of organophosphorus nerve agent degradation products for gas chromatography with ICPMS and TOF-MS detection. Anal Bioanal Chem 388(4):809-23. PMID:17356819
  • Shah M, Meija J, Caruso JA. 2007. Relative mass defect filtering of high-resolution mass spectra for exploring minor selenium volatiles in selenium-enriched green onions. Anal Chem 79(3):846-853. PMID:17263309

2006

  • Gergely V, Kubachka KM, Mounicou S, Fodor P, Caruso JA. 2006. Selenium speciation in Agaricus bisporus and Lentinula edodes mushroom proteins using multi-dimensional chromatography coupled to inductively coupled plasma mass spectrometry. J Chromatogr A 1101(1-2):94-102. PMID:16233900
  • Mounicou S, Vonderheide AP, Shann JR, Caruso JA. 2006. Comparing a selenium accumulator plant (Brassica juncea) to a nonaccumulator plant (Helianthus annuus) to investigate selenium-containing proteins. Anal Bioanal Chem 386(5):1367-1378. doi:10.1007/s00216-006-0707-8 PMID:16933129
  • Mueller-Spitz SR, Vonderheide AP, Shann JR, Caruso JA, Kinkle BK. 2006. Use of SEC-ICP-MS with a collision cell for determining the interaction of chromium with DNA extracted from metal-contaminated soils. Anal Bioanal Chem 386(1):142-51. PMID:16868731
  • Munoz AS, Kubachka KM, Wrobel K, Corona JG, Ketavarapu Yathavakilla SV, Caruso JA, Wrobel K. 2006. Se-enriched mycelia of Pleurotus ostreatus: distribution of selenium in cell walls and cell membranes/cytosol. J Agric Food Chem 54(9):3440-3444. doi:10.1021/jf052973u PMID:16637705
  • Shah M, Meija J, Cabovska B, Caruso JA. 2006. Determination of phosphoric acid triesters in human plasma using solid-phase microextraction and gas chromatography coupled to inductively coupled plasma mass spectrometry. J Chromatogr A 1103(2):329-336. PMID:16337211

2005

  • Fischer JM, Robbins SB, Al-Zoughool M, Kannamkumarath SS, Stringer SL, Larson JS, Caruso JA, Talaska G, Stambrook PJ, Stringer JR. 2005. Co-mutagenic activity of arsenic and benzo[a]pyrene in mouse skin. Mutat Res 588(1):35-46. doi:10.1016/j.mrgentox.2005.09.003 PMID:16242380
  • Ketavarapu Yathavakilla SV, Shah M, Mounicou S, Caruso JA. 2005. Speciation of cationic selenium compounds in Brassica juncea leaves by strong cation-exchange chromatography with inductively coupled plasma mass spectrometry. J Chromatogr A 1100(2):153-159. PMID:16198358
  • Wuilloud RG, Shah M, Kannamkumarath SS, Altamirano JC. 2005. The potential of inductively coupled plasma-mass spectrometric detection for capillary electrophoretic analysis of pesticides. Electroanalysis 26(7-8):1598-1605. PMID:15765486

2004

  • Evans CD, LaDow K, Schumann BL, Savage R, Caruso JA, Vonderheide AP, Succop P, Talaska G. 2004. Effect of arsenic on benzo[a]pyrene DNA adduct levels in mouse skin and lung. Carcinogenesis 25(4):493-497. doi:10.1093/carcin/bgg199 PMID:14578163
  • Grant TD, Montes-Bayon M, LeDuc DL, Fricke MW, Terry N, Caruso JA. 2004. Identification and characterization of Se-methyl selenomethionine in Brassica juncea roots. J Chromatogr A 1026(1-2):159-166. PMID:14763742
  • Grant TD, Wuilloud RG, Wuilloud JC, Caruso JA. 2004. Investigation of the elemental composition and chemical association of several elements in fulvic acids dietary supplements by size-exclusion chromatography UV inductively coupled plasma mass spectrometric. J Chromatogr A 1054(1-2):313-319. PMID:15553158
  • Kannamkumarath SS, Wrobel K, Wrobel K, Caruso JA. 2004. Speciation of arsenic in different types of nuts by ion chromatography-inductively coupled plasma mass spectrometry. J Agric Food Chem 52(6):1458-1463. PMID:15030196
  • Kannamkumarath SS, Wuilloud RG, Caruso JA. 2004. Studies of various elements of nutritional and toxicological interest associated with different molecular weight fractions in Brazil nuts. J Agric Food Chem 52(19):5773-5780. PMID:15366819
  • Kannamkumarath SS, Wuilloud RG, Jayasinghe S, Caruso JA. 2004. Fast speciation analysis of iodophenol compounds in river waters by capillary electrophoresis-inductively coupled plasma-mass spectrometry with off-line solid-phase microextraction. Electrophoresis 25(12):1843-1851. PMID:15213983
  • Kannamkumarath SS, Wuilloud RG, Stalcup AM, Caruso JA, Patel H, Sakr A. 2004. Determination of levothyroxine and its degradation products in pharmaceutical tablets by HPLC-UV-ICP-MS. J Anal At Spectrom 19(1):107-113.
  • LeDuc DL, Montes-Bayon M, Meija J, Malit MF, Wu CP, Abdel-Samie M, Chiang E, Neuhierl B, Bock A, Caruso JA, Terry N, Tagmount A, deSouza M. 2004. Overexpression of selenocysteine methyltransferase in Arabidopsis and Indian mustard increases selenium tolerance and accumulation. Plant Physiol 135(1):377-383. PMID:14671009
  • Meija J, Beck TL, Caruso JA. 2004. Interpretation of alkyl diselenide and selenosulfenate mass spectra. J Am Soc Mass Spectrom 15(9):1325-1332. PMID:15337513
  • Meija J, Caruso JA. 2004. Deconvolution of isobaric interferences in mass spectra. J Am Soc Mass Spectrom 15(5):654-658. PMID:15121194
  • Meija J, Caruso JA. 2004. Selenium and sulfur trichalcogen ides from the chalcogenide exchange reaction. Inorg Chem 43(23):7486-7492. PMID:15530099
  • Montes-Bayon M, Meija J, LeDuc DL, Terry N, Caruso JA, Sanz-Medel A. 2004. HPLC-ICP-MS and ESI-Q-TOF analysis of biomolecules induced in Brassica juncea during arsenic accumulation. J Anal At Spectrom 19(1):153-158.
  • Mounicou S, Meija J, Caruso JA. 2004. Preliminary studies on selenium-containing proteins in Brassica juncea by size exclusion chromatography and fast protein liquid chromatography coupled to ICP-MS. Analyst 129(2):116-123. PMID:14752553
  • Richardson DD, Kannamkumarath SS, Wuilloud RG, Caruso JA. 2004. Hydride generation interface for speciation analysis coupling capillary electrophoresis to inductively coupled plasma mass spectrometry. Anal Chem 76(23):7137-7142. PMID:15571371
  • Sadi BM, Vonderheide AP, Caruso JA. 2004. Analysis of phosphorus herbicides by ion-pairing reversed-phase liquid chromatography coupled to inductively coupled plasma mass spectrometry with octapole reaction cell. J Chromatogr A 1050(1):95-101. PMID:15503930
  • Shah M, Kannamkumarath SS, Wuilloud JC, Wuilloud RG, Caruso JA. 2004. Identification and characterization of selenium species in enriched green onion (Allium fistulosum) by HPLC-ICP-MS and ESI-ITMS. J Anal At Spectrom 19(3):381-386.
  • Vonderheide AP, Meija J, Tepperman K, Puga A, Pinhas AR, States JC, Caruso JA. 2004. Retention of Cr(III) by high-performance chelation ion chromatography interfaced to inductively-coupled plasma mass spectrometric detection with collision cell. J Chromatogr A 1024(1-2):129-137. PMID:14753715
  • Wilburn RT, Vonderheide AP, Soman RS, Caruso JA. 2004. Speciation of selenium in the mushroom Boletus edulis by high-performance liquid chromatography coupled to inductively coupled plasma-mass spectrometry with a collision cell. Applied Spectroscopy 58(10):1251-1255. PMID:15527527
  • Wuilloud JC, Wuilloud RG, Vonderheide AP, Caruso JA. 2004. Gas chromatography/plasma spectrometry - an important analytical tool for elemental speciation studies. Spectrochimica Acta Part B: Atomic Spectroscopy 59(6):755-792.
  • Wuilloud RG, Kannamkumarath SS, Caruso JA. 2004. Multielemental speciation analysis of fungi porcini (Boletus edulis) mushroom by size exclusion liquid chromatography with sequential on-line UV-ICP-MS detection. J Agric Food Chem 52(5):1315-1322. PMID:14995139
  • Wuilloud RG, Kannamkumarath SS, Caruso JA. 2004. Speciation of essential and toxic elements in edible mushrooms: size-exclusion chromatography separation with on-line UV-inductively coupled plasma mass spectrometry detection. Applied Organometallic Chemistry 18(4):156-165.
  • Wuilloud RG, Kannamkumarath SS, Caruso JA. 2004. Speciation of nickel, copper, zinc, and manganese in different edible nuts: a comparative study of molecular size distribution by SEC-UV-ICP-MS. Anal Bioanal Chem 379(3):495-503. PMID:15048546
  • Wuilloud RG, Selar N, Kannamkumarath SS, Caruso JA. 2004. Determination of 2,4,6-triiodophenol and its metabolites in human urine by anion-exchange chromatography with ICP-MS detection. J Anal At Spectrom 19(11):1442-1447.

2003

  • Caruso JA, Klaue B, Michalke B, Rocke DM. 2003. Group assessment: elemental speciation. Ecotoxicol Environ Saf 56:32-44. PMID:12915138
  • Meija J, Bryson J, Vonderheide AP, Montes-Bayon M, Caruso JA. 2003. Studies of selenium containing volatiles in roasted coffee. J Agric Food Chem 51(17):5116-5122. PMID:12903978
  • Montes-Bayon M, Caruso JA. 2003. Elemental speciation studies - new directions for trace metal analysis. Ecotoxicol Environ Saf 56(1):148-163. PMID:12915148
  • Montes-Bayon M, DeNicola K, Caruso JA. 2003. Liquid chromatography-inductively coupled plasma mass spectrometry. J Chromatogr A 1000(1-2):457-476. PMID:12877184
  • Ponce de Leone C, Montes-Bayon M, DeNicola K, Caruso JA. 2003. Sequential extractions of selenium soils: total selenium and speciation measurements with ICP-MS detection. J Environ Monit 5:435-440. PMID:12833987
  • Ponce de Leone C, Vonderheide AP, Caruso JA. 2003. Sample Preparation for Speciation of Selenium. In: Volume XLI of Wilson and Wilson's Comprehensive Analytical Chemistry: Sample Preparation for Trace Analysis. Elsevier, New York, NY. pp.1039-1058.
  • Vonderheide AP, Meija J, Montes-Bayon M, Caruso JA. 2003. Use of optional gas and collision cell for enhanced sensitivity of the organophosphorus pesticides by GC-ICP-MS. J Anal At Spectrom 18(9):1097-1102.
  • Wrobel K, Kannamkumarath SS, Wrobel K, Caruso JA. 2003. Different environmental aspects of trace element speciation analysis by hyphenated techniques. In: Green Chemistry: Environment Friendly Alternatives. Narosa, Kanpur, India.
  • Wrobel K, Kannamkumarath SS, Wrobel K, Caruso JA. 2003. Environmentally friendly sample treatment for speciation analysis by hyphenated techniques. Green Chem 5(2):250-259.
  • Wrobel K, Sadi BM, Wrobel K, Castillo JR, Caruso JA. 2003. Effect of metal ions on the molecular weight distribution of humic substances derived from municipal compost: ultrafiltration and SEC with spectrophotometric and ICP-MS detection. Anal Chem 75(4):761-767. PMID:12622364
  • Wrobel K, Wrobel K, Kannamkumarath SS, Caruso JA. 2003. Identification of selenium species in urine by ion-pairing HPLC-ICP-MS using laboratory-synthesized standards. Anal Bioanal Chem 377(4):670-674. PMID:12937882
  • Wuilloud RG, de Wuilloud JC, Vonderheide AP, Caruso JA. 2003. Determination of iodinated phenol species at parts-per-trillion concentration levels in different water samples by solid-phase microextraction/offline GC-ICP-MS. J Anal At Spectrom 18(9):1119-1124.
  • Yadav JS, Soellner MB, Loper JC, Mishra PK. 2003. Tandem cytochrome P450 monooxygenase genes and splice variants in the white rot fungus Phanerochaete chrysosporium: cloning, sequence analysis, and regulation of differential expression. Fungal Genetics and Biology 38(1):10-21. PMID:12553932

2002

  • B'Hymer C, Caruso JA. 2002. Efficiency study and evaluation of enzyme hydrolysis procedures for selenium enriched yeast using ICP-MS detection. Canadian Journal of Analytical Sciences and Spectroscopy 46:136-144.
  • Brisbin JA, B'Hymer C, Caruso JA. 2002. A gradient anion exchange chromatographic method for the speciation of arsenic in lobster tissue extracts. Talanta 58(1):133-146. PMID:18968740
  • Brisbin JA, Caruso JA. 2002. Comparison of extraction procedures for the determination of arsenic and other elements in lobster tissue by inductively coupled plasma mass spectrometry. Analyst 127(7):921-929. PMID:12173651
  • Day JA, Montes-Bayon M, Vonderheide AP, Caruso JA. 2002. A study of method robustness for arsenic speciation in drinking water samples by anion exchange HPLC-ICP-MS. Anal Bioanal Chem 373(7):664-668. PMID:12185580
  • Kannamkumarath SS, Wrobel K, Wrobel K, B'Hymer C, Caruso JA. 2002. Capillary electrophoresis-inductively coupled plasma-mass spectrometry: an attractive complementary technique for elemental speciation analysis. J Chromatogr A 975(2):245-266. PMID:12456080
  • Kannamkumarath SS, Wrobel K, Wrobel K, Vonderheide AP, Caruso JA. 2002. HPLC-ICP-MS determination of selenium distribution and speciation in different types of nut. Anal Bioanal Chem 373(6):454-460. PMID:12172680
  • Meija J, Montes-Bayon M, LeDuc DL, Terry N, Caruso JA. 2002. Simultaneous monitoring of volatile selenium and sulfur species from se accumulating plants (wild type and genetically modified) by GC/MS and GC/ICPMS using solid-phase microextraction for sample introduction. Anal Chem 74(22):5837-5844. PMID:12463370
  • Montes-Bayon M, Grant TD, Meija J, Caruso JA. 2002. Selenium in plants by mass spectrometric techniques: developments in bio-analytical methods. J Anal At Spectrom 17(9):1015-1023.
  • Montes-Bayon M, LeDuc DL, Terry N, Caruso JA. 2002. Selenium speciation in wild-type and genetically modified se accumulating plants with HPLC separation and ICP-MS/ES-MS detection. J Anal At Spectrom 17(8):872-879.
  • Montes-Bayon M, Yanes EG, Ponce de Leone C, Jayasimhulu K, Stalcup AM, Shann JR, Caruso JA. 2002. Initial studies of selenium speciation in Brassica Juncea by LC with ICP-MS and ES-MS detection: an approach for phytoremediation. Anal Chem 74(1):107-113. PMID:11795777
  • Ponce de Leone C, Montes-Bayon M, Caruso JA. 2002. Elemental speciation by chromatography with inductively coupled plasma mass spectrometry detection. J Chromatogr A 974(1-2):1-21. PMID:12458926
  • Ponce de Leone C, Montes-Bayon M, Caruso JA. 2002. Trace element determination in Vitamin E by ICP-MS. Anal Bioanal Chem 374(2):230-234. PMID:12324842
  • Ponce de Leone C, Montes-Bayon M, Paquin C, Caruso JA. 2002. Selenium incorporation into Saccharomyces cerevisiae cells: a study of different incorporation methods. J Appl Microbiol 92(4):602-610. PMID:11966899
  • Radike M, Warshawsky D, Caruso JA, Goth-Goldstein R, Reilman R, Collins T, Yaeger M, Wang J, Vela NP, Olson LK, Schneider JR. 2002. Distribution and accumulation of a mixture of arsenic, cadmium, chromium, nickel, and vanadium in mouse small intestine, kidneys, pancreas, and femur following oral administration in water or feed. J Toxicol Environ Health A 65(23):2029-2052. PMID:12490046
  • Sadi BM, Wrobel K, Wrobel K, Kannamkumarath SS, Castillo JR, Caruso JA. 2002. SEC-ICP-MS studies for elements binding to different molecular weight fractions of humic substances in compost extract obtained from urban solid waste. J Environ Monit 4(6):1010-1016. PMID:12509059
  • Vonderheide AP, Montes-Bayon M, Caruso JA. 2002. Development and application of a method for the analysis of brominated flame retardants by fast gas chromatography with ICP-MS detection. J Anal At Spectrom 17(11):1480-1485.
  • Vonderheide AP, Montes-Bayon M, Caruso JA. 2002. Solid-phase microextraction as a sample preparation strategy for the analysis of seleno amino acids by gas chromatography-inductively coupled plasma mass spectrometry. Analyst 127(1):49-53. PMID:11827394
  • Vonderheide AP, Wrobel K, Kannamkumarath SS, B'Hymer C, Montes-Bayon M, Ponce de Leone C, Caruso JA. 2002. Characterization of selenium species in Brazil nuts by HPLC-ICP-MS and ES-MS. J Agric Food Chem 50(20):5722-5728. PMID:12236705
  • Wrobel K, Wrobel K, Caruso JA. 2002. Seleniun speciation in low molecular weight fraction of Se-enriched yeasts by HPLC-ICP-MS: Detection of selenoadenoslymethionine. J Anal At Spectrom 17:1048-1054.
  • Wrobel K, Wrobel K, Parker B, Kannamkumarath SS, Caruso JA. 2002. Determination of As(III), As(V), monomethylarsonic acid, dimethylarsinic acid and arsenobetaine by Ion Pairing HPLC using ICP-MS: Analysis of reference materials, fish tissues, and urine. Talanta 58(5):899-907. PMID:18968822
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